Thu., Jan. 15, 2015

Music:
Wilsen "House on a Hill"; Laura Marling "Blackberry Stone"; Lucius "Turn It Around"; The Bangles "Hazy Shade of Winter" the 1987 version is what you heard in class but the Live version recorded in 2000 is also good.   There was time for "Hello, I Love You" from The Doors before the 9:30 class.

I hope you had a chance to see the fog on Wednesday morning.  Fog is pretty rare in Tucson; a once every 2 years or so phenomenon.   Fog like we had yesterday forms when moist air at ground level cools to the dew point temperature (dew point temperature was introduced in today's class).  The air yesterday was moister than normal because it had rained a little bit the night before. 


Looking east from my house in central Tucson Wednesday morning
Looking west.  Visibility was about 1/4 mile.



Course Introduction
Welcome to the Spring 2015 edition of ATMO 170 Introduction to Weather & Climate.  We first briefly discussed the Course Information handout.  Please read through that information carefully on your own and let me know if you have any questions.

A textbook is not required for this class.  If you want to get a more complete picture of the subject than we will have time to do in class, you might want to purchase one of the textbooks that are being used in the other ATMO 170A1 sections.  Or if you'd like to borrow one of the copies of introductory level textbooks that I have in my office, just let me know.  Otherwise you should be able to do perfectly well in the class by reading the online notes.  It is important to read through the online notes even if you are in class.

A set of photocopied ClassNotes (available in the ASUA Bookstore in the Student Union) is required.  You should try to purchase a copy as soon as you can because we will probably be using the first page in class next Tuesday.   You might know someone with notes from last Fall's class; they'll work fine this semester also.

Writing is an important part of this class and is described in more detail on the Writing Requirements handout Please have a careful look at that also and let me know if you have any questions.

The first half of your writing grade is an experiment report.  You only need to do one of the experiments, so think about which of the experiments (listed on the handout) you might like to do.  I'll bring signup sheets to class next Tuesday.  I'm also planning on bringing about 40 - 45 sets of materials next Tuesday.  Materials checkout is first come first served. 


The so-called One Side of One Page (1S1P) reports make up the second part of your writing grade.  Topics will appear periodically during the semester on the class webpage.  As you write reports you will earn points (the exact number of points will depend on the topic and the quality of your report).  Your goal should be to earn 45 1S1P pts, the maximum number allowed, by the end of the semester.

You'll be allowed to revise and raise your grade on the first draft of your experiment report.  So you should be able to earn a pretty high score on that.  And, unless you procrastinate, you can just keep on writing 1S1P reports until you've earned 45 points.  There's no good reason not to earn a high writing grade.



Grade example

Your final grade in this class will depend on your quiz scores, how much extra credit you earn (from optional take home and in class assignments), your writing grade, and (perhaps) your score on the final exam.  A sample grade report from the Fall 2014 class is shown below (the numbers are class averages).


Doe_J
quiz1 -43 (155 pts possible) 72.3%   quiz scores
quiz2 -50 (170 pts possible) 70.6%
quiz3 -51 (185 pts possible) 74.4%
quiz4 -45 (175 pts possible) 74.3%

1.5 EC points      extra credit earned on optional assignments

writing scores
writing scores: 34.0 (expt/book report) + 45.0 (1S1P pts)
writing grade: 98.8%

overall averages (prior to the Final Exam)
average (no quiz scores dropped): 78.1% + 1.5 = 79.6%    
average (lowest quiz score dropped): 80.0% + 1.5 = 81.5%
you DO need to take the final exam

27.0 pts missed on the final exam = 73.0%     exam score
overall average is 79.8%
      final grade

The 4 quiz grades are shown at the top. 

The next entry shows that the average student earned 1.5 points of extra credit points.  You will have the opportunity to earn at least 3 extra credit points. 

A score of 34 points on the experiment report and 45 1S1P pts resulted in a writing percentage grade of 98.8%.  There's no good reason not to end up with a writing score close to 100% (over even greater than 100%)


The overall average without any quiz scores dropped is shown next.  Since the result, 79.6%, is less than 90.0% the average student last fall did have to take the final exam  The second average (with the lowest score dropped) is a little higher, 81.5%.

If you do well on the final exam it will count 40% of your overall grade (trying to maximize the benefit it can have).  If you don't do so well on the final it only counts 20% (minimizing the damage it can cause).  In this example the final exam score (73 %) was lower than the 81.5% value, so the final exam only counted 20% and the overall score was 79.8%.  This would be rounded up to 80% and a B. 

Note that even though this average student had C grades on all 4 quizzes and the Final Exam, the student ended up with a B in the class.  That is due largely to the high writing grade and the fact that the student did have some extra credit points.


Comments about the class
Next a couple of comments about the class from Spring 2014:

comment #1 
The important thing is to keep up with material as it's covered in class.  You don't necessarily need to come to class to do this.  You should definitely be reading the online lecture notes on a regular basis.
comment #2
Don't let concerns like this wait until the end of the semester.  Let me or one of the TAs know of your concerns so that they can be addressed during the semester.

"Chapter 1" - the earth's atmosphere

We did cover a little course material in class today just so you can get an idea of how that will work.   If we were using a book we'd start in Chapter 1 and here's some of what we would first be looking at in this course.  






We will come back to the first item - the composition of the atmosphere.
Before we do that however, here are a few questions to get you thinking about the air around you.  This is an example of material that appears in the online notes even though it wasn't covered in class.  I usually insert some red bold text to get your attention.

Example of material appearing in the online notes even though it wasn't covered in class.
Can you see air?

Air is mostly clear, transparent, and invisible (that would be true of the air in the classroom).  Sometimes the air looks foggy, hazy, or smoggy.  In these cases you are "seeing" small water droplets or ice crystals (fog) or small particles of dust or smoke (haze and smog).  The particles themselves may be too small to be seen with the naked eye but are visible because they scatter (redirect) light.  I didn't really mention or explain what that is but it's a pretty important concept and we will learn more about it in a week or so.

And to be completely honest air isn't really invisible.  If you shine a bright light through enough air, such as when sunlight shines through the atmosphere, the air (the sky) appears blue.  This is a little more complicated form of scattering of sunlight by air molecules.  We'll come back to this later as well.


Can you smell air?

I don't think you can smell or taste air (air containing nitrogen, oxygen, water vapor, argon and carbon dioxide).  But there are also lots of other odors you can sometimes smell (freshly cut grass, hamburgers on a grill, etc).  I don't consider these normal constituents of the atmosphere.  You can probably also smell certain pollutants.  I suspect our sense of smell is sensitive enough for us to detect certain air pollutants even when their concentration is very small (probably a good thing because many of them are poisonous). 

Natural gas (methane) used in hot water heaters, some stoves, and furnaces is odorless.  A chemical (mercaptan) is added to natural gas so that you can smell it and know when there is a leak before it builds up to a concentration that could cause an explosion. 

Can you feel air


It is harder to answer this question.  We're always in contact with air.  Maybe we've grown so accustomed to it we aren't aware of how it feels.  We can certainly feel whether the air is hot or cold, but that have more to do with energy exchange between us and our surroundings.  And we can feel wind. 

In a week or two we will see that, here in the classroom, air pressure is pressing on every square inch of our bodies with 12 or 13 pounds of force.  If that were to change suddenly I'm pretty sure we'd feel it and it would probably really hurt.



What are the 5 most abundant gases in air?
Let's start with the most abundant gas in the atmosphere.  I poured some of this same material (in liquid form) into a Styrofoam cup.  Here's a photo I took back in my office.






You can see the liquid, it's clear, it looks like water.  I had the impression that a lot of students knew this was liquid nitrogen.  It's very cold and begins to boil (evaporate) at -321o F.

The most abundant gas in the atmosphere is nitrogen.  We'll use liquid nitrogen in several class demonstration this semester mostly because it is so cold. 

Nitrogen was discovered in 1772 by Daniel Rutherford (a Scottish botanist).  Atmospheric nitrogen is relatively unreactive and is sometimes used to replace air in packaged foods to preserve freshness.  You don't need to worry about details like this for a quiz.

Oxygen is the second most abundant gas in the atmosphere.  Oxygen is the most abundant element (by mass) in the earth's crust, in ocean water, and in the human body.  






from: http://www.webelements.com/oxygen/
The web elements site credits Prof. James Marshall's Walking Tour of the Elements.
from: http://en.wikipedia.org/wiki/Oxygen
Wikipedia credits Dr. Warwick Hillier of Australia National University

A couple of photographs of liquid oxygen are shown above (it boils at -297o F).  It has a (very faint) pale blue color (I was pretty disappointed because I had imagined it might be a deep vivid blue).  I'd love to bring some liquid oxygen to class but I'm not sure it's available on campus.  Also oxygen is very reactive and I suspect you'd need to be very careful with liquid oxygen.

When heated (such as in an automobile engine) the oxygen and nitrogen in air react to form compounds such as nitric oxide (NO), nitrogen dioxide (NO2), and nitrous oxide (N2O).  Together as a group these are called oxides of nitrogen; the first two are air pollutants, the last is a greenhouse gas.

Here is a complete list of the 5 most abundant gases in air.  And a note about the figures you'll find in these online notes.  They may differ somewhat from what was done in class.  I often redraw them after class, or use neater versions from a previous semester for improved clarity (and so I can get the notes online more quickly).



Water vapor and argon are the 3rd and 4th most abundant gases in the atmosphere.  A 2% water vapor concentration is listed above but it can vary from near 0% to as high as 3% or 4%.  Water vapor is, in many locations, the 3rd most abundant gas in air.  In Tucson most of the year, the air is dry enough that argon is in 3rd position and water vapor is 4th.

Water vapor, a gas, is invisible.   Water is the only compound that exists naturally in solid, liquid, and gaseous phases in the atmosphere.

Argon is an unreactive noble gas (helium, neon, krypton, xenon, and radon are also inert gases). 





Here's a picture of solid argon (argon "ice").  It melts at melts at -309o F and evaporates at -302o F; it's doing both in this picture. (image source).




This is solid carbon dioxide, better known as dry ice.  It doesn't melt, it sublimates.  I.e. it changes directly from solid to gas. (source)

The concentration of carbon dioxide is much smaller than the other gases (you don't need to remember the actual value).  That doesn't mean it isn't important.  We'll spend a lot of time this semester talking about water vapor and also carbon dioxide.  Water vapor and carbon dioxide are the two best known and most important greenhouse gases.  The greenhouse effect warms the earth.  Concentrations of greenhouse gases such as carbon dioxide are increasing and there is concern this will strengthen the greenhouse effect and cause global warming.  That's a topic we'll look at during the semester.

Here's a little more explanation (from Wikipedia) of why noble gases are so unreactive.  Don't worry about all these additional details, none of this was covered in class.  The noble gases have full valence electron shells.  Valence electrons are the outermost electrons of an atom and are normally the only electrons that participate in chemical bonding.   Atoms with full valence electron shells are extremely stable and therefore do not tend to form chemical bonds and have little tendency to gain or lose electrons (take electrons from or give electrons to atoms of different materials).







Noble gases are often used used in neon signs; argon produces a blue color.  The colors produced by Argon (Ar), Helium (He), Kryton (Kr), Neon (Ne) and Xenon (Xe), which are also noble gases, are shown above (source of the images).   The inert gases don't react with the metal electrodes in the bulbs.  Neon bulbs and fluorescent bulbs (including energy saving CFLs) often also contain mercury vapor (which means you should dispose of them carefully when they burn out).  The mercury vapor emits ultraviolet light that strikes phosphors of different kinds on the inside of the bulb.  Different colors are emitted depending on the particular type of phosphor used in the bulb.



If we were using a textbook we'd probably find something like the following table near the beginning of the book ( I found this table a few years ago in a Wikipedia article about the earth's atmosphere ).

 
Composition of dry atmosphere, by volume
ppmv: parts per million by volume (note: volume fraction is equal to mole fraction for ideal gas only, see volume (thermodynamics))
Gas Volume
Nitrogen (N2) 780,840 ppmv (78.084%)
Oxygen (O2) 209,460 ppmv (20.946%)
Argon (Ar) 9,340 ppmv (0.9340%)
Carbon dioxide (CO2) 394.45 ppmv (0.039445%)
Neon (Ne) 18.18 ppmv (0.001818%)
Helium (He) 5.24 ppmv (0.000524%)
Methane (CH4) 1.79 ppmv (0.000179%)
Krypton (Kr) 1.14 ppmv (0.000114%)
Hydrogen (H2) 0.55 ppmv (0.000055%)
Nitrous oxide (N2O) 0.325 ppmv (0.0000325%)
Carbon monoxide (CO) 0.1 ppmv (0.00001%)
Xenon (Xe) 0.09 ppmv (9×10−6%) (0.000009%)
Ozone (O3) 0.0 to 0.07 ppmv (0 to 7×10−6%)
Nitrogen dioxide (NO2) 0.02 ppmv (2×10−6%) (0.000002%)
Iodine (I2) 0.01 ppmv (1×10−6%) (0.000001%)
Ammonia (NH3) trace
Not included in above dry atmosphere:
Water vapor (H2O) ~0.40% over full atmosphere, typically 1%-4% at surface


I like our list of the 5 most abundant gases better.  It's much more manageable.  There is almost too much information in a chart like this, you might be overwhelmed and not remember much.  Also unless you are familiar with the units on the numbers they might be confusing.  And notice you don't find water vapor in 3rd or 4th position near the top of the chart.  That's because this is a list of the gases in dry air.  Unless you're very attentive, you might miss that fact and might not see water vapor way down at the bottom of the chart.
 

If you click on the link above to the Wikipedia article on the earth's atmosphere you'll find that the list above has been replaced with a shorter simpler list (much more like the one we created in class).



Dew point temperature

Water plays an important role in the formation of clouds, storms, and weather.  Meteorologists are very interested in knowing and keeping track of how much water vapor is in the air at a particular place and time.  One of the variables they use is the dew point temperature.  The value of the dew point gives you an idea of how much water vapor is actually in the air.  A high dew point value means more water vapor in the air and higher the water vapor concentration.




The chart below gives a rough equivalence between dew point temperature and percentage concentration of water vapor in the air.  And I did mess the table up in class, the correct version is shown below.

I should have remembered that water vapor concentration doubles every time the dew point temperature increases 20o F, I would have gotten it right.

Air temperature will always be equal to or warmer than the dew point temperature.  Experiencing 80o F dew points would be very unpleasant and possibly life threatening because your body might not be able to cool itself ( the air temperature would probably be in the 90s or maybe even warmer). 
You could get heatstroke and die.


Click here to see current dew point temperatures across the U.S.  Here's a link concerning unusually high, even record setting dew point temperatures. 

Some additional information not mentioned in class.  At one time the dew point temperature was used to identify the official start of the summer monsoon season in Tucson (the summer thunderstorm season).  A monsoon is a seasonal change in the direction of the prevailing winds.  Most of the year in Tucson winds come from the west and are dry.  For 2 or 3 months in the summer the winds turn and blow from the east or southeast and the air is much moister.  During most of the year the dew point will fall between 25o F and 45o F.  Dew points in the summer usually range between 55o F and 65o F or 70o F.   Traditionally the summer monsoon would start when the daily average dew point remained at or above 54 F for three days in a row.

Dew point temperature continued

Now let's go back to the cup of liquid nitrogen









We can see liquid nitrogen but we can't see the nitrogen gas being produced by the evaporation of liquid nitrogen.  The white cloud that surrounds the cup of liquid nitrogen isn't nitrogen gas, what is it?  There was also some frost or snow on the side of the cup, it and the cloud are made of the same material.








The white cloud isn't water vapor because water vapor, a gas, is invisible just like nitrogen gas.  When the air is cooled however, by coming into contact with the liquid nitrogen, the water vapor condenses and forms small droplets of water (liquid) or ice crystals (solid).  That's what you are able to see, a cloud composed of water droplets or ice crystals.

We're seeing a demonstration of the dew point's second job.




If you cool air next to the ground to its dew point, water vapor will condense and coat the ground with water.  The ground will be covered with dew.  If a little thicker layer of air is cooled fog will form.

Here's a link to an article about Wednesday's fog that appeared in the Arizona Daily Star.  This type of fog is called radiation fog or valley fog.  The fog cloud is often very thin.  You can't see very far if you look horizontally, but you can often look up through the fog and sometimes see blue sky.


Closing remarks and Pluto's Gate to Hell

We were nearing a full hour at this point which is probably enough for the first day of class.

When you have a free moment try to recall the 5 most abundant gases in air without looking at your notes.  Then try to remember something about each of them.  You'll find what I think is a reasonable list at the end of today's notes.  Try to remember the two jobs of the dew point temperature.  Doing this will dramatically increase the odds of remembering this information a week or two from now.

Pluto's Gate to Hell was discovered in early 2013 at the ancient city of Hierapolis in southwestern Turkey (Pluto was the Roman god of the underworld, he was called Hades by the Greeks).  None of what follows was covered in class.





The picture above at left shows the site as it appears now (source of this photograph).  The gate is the opening in the wall near the center of the picture.  The site as it might have appear in ancient times is shown above at right.  This photograph, credited to Francesco D'Andria, the lead Italian archaeologist that announced the discovery in March 2013, is found in a news report from the National Geographic Society.

The "gate" was built on top of a cavern and, in ancient times, a mist of deadly vapors could be seen coming from the cave (the mist is shown in the right picture above).  Here's a quote from the Slate article where I first read about the discovery:
"Two millennia ago, visitors to Pluto's Gate could buy small birds or other animals (the sale of which supported the temple) and test out the toxic air that blew out of the mysterious cavern.  Only the priests, high and hallucinating on the fumes, could stand on the steps by the opening to hell.  They would sometimes lead sacrificial bulls inside, later pulling out their dead bodies in front of an awed crowd.

As the Greek geographer, philosopher, and prolific traveler Strabo, who lived from 64/63 B.C. to 24 A.D., so enticingly described it: 'This space is full of a vapor so misty and dense that one can scarcely see the ground.  Any animal that passes inside meets instant death.  I threw in sparrows and they immediately breathed their last and fell.' "
The Italian archaeologists working at the site would occasionally notice birds dying if they flew into the vapors coming from the came.  The deadly gas was carbon dioxide.  Carbon dioxide is not ordinarily thought of as a poisonous gas but in high enough concentrations it can asphyxiate you (cause you to suffocate). 



Here's what you might be able to recall about the 5 most abundant gases in our atmosphere.