Friday, Mar. 30, 2007

The Experiment #4 reports are due next Monday.  If you have returned your materials yet and picked up the supplementary information sheet, Monday morning will be your last opportunity.  You will need to come to my office (PAS 588) leave your materials in the box just inside the door to the left, and help yourself to a copy of the supplementary information sheet.




The collision coalescence process works best in a cloud filled with cloud droplets of different sizes.  As we saw in a short video the larger droplets fall faster than the small droplets.  The large droplets overtake and collide with the smaller ones. The droplets then stick together and form any even larger droplet that will fall faster than before and sweep out a larger volume.  In this accelerating growth process an above-average size droplet can quickly turn into a raindrop.

The figure below shows the two precipitation producing clouds: nimbostratus (Ns) and cumulonimbus (Cb).  Ns clouds are thinner and have weaker updrafts than Cb clouds.  The largest raindrops fall from Cb clouds because the droplets spend more time in the cloud growing.


Raindrops grow up to about 1/4 inch in diameter.  When drops get larger than that, wind resistance flattens out the drop as it falls toward the ground.  The drop becomes unstable and breaks apart into several smaller droplets.  Solid precipitation particles that are made of ice can get much larger than 1/4 inch in diamter.

Before learning about the second precipitation producing process, the ice crystal process, we need to look at the structure of cold clouds.



The top of the thunderstorm is so cold (colder than -40 F) that there are just ice crystals there.  The bottom is warm enough (warmer than freezing) to just contain water droplets.  The interesting part of the thunderstorm and the nimbostratus cloud is the part that contains both supercooled water droplets (water that has been cooled to below freezing but hasn't frozen) and ice crystals.  This is called the mixed phase region.  This is where the ice crystal process will be able to produce precipitation.  This is also where the electrical charge that results in lightning is generated.

The supercooled water droplets aren't able to freeze even though they have been cooled below freezing.  This is because it is much easier for small droplets of water to freeze onto an ice crystal nucleus (just like it is easier for water vapor to condense onto condensation nuclei rather than condensing and forming a small droplet of pure water).  Not just any material will work as an ice nucleus however.  The material must have a crystalline structure that is like that of ice.






Back before there was NATS 101 there was a course called ATMO 171 (also an Introduction to Weather and Climate class) and a one hour lab course ATMO 171L.  The figure above shows an experiment the ATMO 171L students used to do.  The students would put a bunch of distilled water drops on one side of an aluminum stand.  They would put an equal number of water drops containing silver iodide on the other side of the stand. Silver iodide is one of the unusual materials that acts as an ice nucleus.

The stand was put into a styrofoam ice chest and some liquid nitrogen was poured in to cool the stand.  The students could monitor the temperature of the top platform using a thermometer stuck into a hole drilled in the side (not shown in the figure above). 

We watched a short video showing the freezing of the drops.  The water drops containing silver iodide froze before the distilled water drops.  The silver iodide drops still had to be cooled to be 0 C before freezing (average freezing temperature was around -5 to -10 C).  The average freezing temperature of the distilled water drops was between -10 and -20 C.

Now we'll see how the ice crystal process works.



The first figure above (see p.101 in the photocopied Class Notes) shows a water droplet in equilibrium with its surroundings..The droplet is evaporating (the 3 green arrows in the figure).  The rate of evaporation will depend on the temperature of the water droplet.  The droplet is surrounded by air that is saturated with water vapor (the droplet is inside a cloud where the relative humidity is 100%).  This means there is enough water vapor to be able to supply 3 arrows of condensation.

The next figure shows what is required for an ice crystal (at the same temperature) to be in equilibrium with its surroundings.  First the ice crystal won't evaporate as rapidly as the water droplet (only one arrow is shown).  Going from ice to water vapor is a bigger jump than going from water to water vapor.  There won't be as many ice molecules with enough energy to make that jump.  A sort of analogous situation is shown in the figure below (many people could jump up a 1 foot step, fewer people would be able to jump up a 3 foot step).

To be in equilibrium only one arrow of condensation is needed.  There doesn't need to be as much water vapor in the air surrounding the ice crystal to supply this lower rate of condensation.



Now what happens in the mixed phase region of a cold cloud is that ice crystals find themselves in the very moist surroundings needed for water droplet equilibrium. This is shown below.


The water droplet is in equilibrium (3 arrows of evaporation and 3 arrows of condensation) with the surroundings.  The ice crystal is evaporating more slowly than the water droplet.  Because the ice crystal is in the same surroundings as the water droplet water vapor will be condensing onto the ice crystal at the same rate as onto the water droplet.  The ice crystal isn't in equilibrium, condensation exceeds evaporation and the ice crystal will grow.

The equal rates of condensation are shown in the figure below using the earlier analogy.