The air in #4 is saturated, the rates of evaporation and condensation are equal, and the relative humidity is 100%. 

OK we take off the cover and add water vapor to the air in #4 .  This supersaturates the air, raises the relative humidity over 100%.  This is shown in #5.  With more water vapor, there will be more condensation.  Note there are three arrows of condensation in #5 above and only 2 arrows of evaporation. 

Since there is more condensation than evaporate the amount of water vapor in the air will decrease.  It will eventually return to the situation in #4 where the amounts of evaporation and condensation are equal.  The relative humidity will again be 100%